A total synthesis of (±)-isocomene(1) and (±)-β-isocomene (2) employing a chelation-controlled regioselective epoxide–carbonyl rearrangement as the key step has been realized.
Y. Tobe, T. Yamashita, K. Kakiuchi and Y. Odaira, J. Chem. Soc., Chem. Commun., 1985, 898 DOI: 10.1039/C39850000898
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