Issue 9, 1985

Preparation and structure of (η5-C5H5)4Cr4O32-C5H4), a hydrocarbon derivative of the cubane cluster (η5-C5H5)4Cr4O4

Abstract

Oxidation of (cp)2Cr (cp =η5-C5H5) with Me3NO produces a mixture of the previously reported (cp)4Cr4O4 and (cp)4Cr4O32-C5H4); the structure of the latter has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 597-598

Preparation and structure of (η5-C5H5)4Cr4O32-C5H4), a hydrocarbon derivative of the cubane cluster (η5-C5H5)4Cr4O4

F. Bottomley, D. E. Paez, L. Sutin and P. S. White, J. Chem. Soc., Chem. Commun., 1985, 597 DOI: 10.1039/C39850000597

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