SCHEDULED MAINTENANCE
Model calculations using the 6-31 + G* basis set suggest that, in contrast to the situation for the isolated chloromethane radical anion in condensed phases, there is a barrier to the dissociation of ion paired MeCl–˙ into a methyl radical and a chloride ion.
T. Clark and G. Illing, J. Chem. Soc., Chem. Commun., 1985, 529 DOI: 10.1039/C39850000529
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