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Issue 9, 1985
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The reduction of chloroalkanes by alkali metals: a model ab intio study

Abstract

Model calculations using the 6-31 + G* basis set suggest that, in contrast to the situation for the isolated chloromethane radical anion in condensed phases, there is a barrier to the dissociation of ion paired MeCl˙ into a methyl radical and a chloride ion.

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Article information


J. Chem. Soc., Chem. Commun., 1985, 529-530
Article type
Paper

The reduction of chloroalkanes by alkali metals: a model ab intio study

T. Clark and G. Illing, J. Chem. Soc., Chem. Commun., 1985, 529
DOI: 10.1039/C39850000529

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