The equilibrium isotope effect on the degenerate rearrangement of the 1-(2,3-dimethylclopropyl)ethyl cation is compared with theoretical and other experimental data and the implications for the interpretation of kinetic isotope effects and for the investigation of hyperco-ordinated carbocations are discussed.
H. Siehl and E. Koch, J. Chem. Soc., Chem. Commun., 1985, 496 DOI: 10.1039/C39850000496
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