Benzyl ketones can be synthesised efficiently from benzene and α-diazoketones with sequential catalysis by rhodium(II) trifluoroacetate and trifluoroacetic acids; the process involves cycloheptatrienyl intermediates.
M. A. McKervey, D. N. Russell and M. F. Twohig, J. Chem. Soc., Chem. Commun., 1985, 491 DOI: 10.1039/C39850000491
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