Pyrolysis of tetrakis(methyldichlorophosphine)nickel(0) with decacarbonyldirhenium leads to the formation of the tetranuclear complex Re4Cl2(CO)15{MePP(Me)PMe}, the eight-electron donor triphosphine ligand forming a four-membered cyclorhenatriphosphine ring.
N. J. Taylor, J. Chem. Soc., Chem. Commun., 1985, 476 DOI: 10.1039/C39850000476
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