Issue 5, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

An unusual CuII-promoted desulphurisation of thiourea: synthesis and crystal structure of di-µ-hydrogencyanamido(1–)-bis[(N,N′,N″-trimethyl-1,4,7-triazacyclononane)copper(II)] di-perchlorate monohydrate

Phalguni Chaudhuri,   Karl Wieghardt,   Bernhard Nuber  and  Johannes Weiss  

Abstract

The complex [Cu2(C9H21N3)2(µ-HNCN)2](ClO4)2·H2O has been synthesized by reaction of [Cu(C9H21N3)(H2O)2]2+ with thiourea in the presence of oxygen in aqueous solution with concomitant formation of elemental sulphur; the complex has been characterized by X-ray crystallography, showing that two CuII centers are connecter via two bridging hydrogencyanamido(1–) ligands.

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Article information

DOI
https://doi.org/10.1039/C39850000265
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 265-266

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An unusual CuII-promoted desulphurisation of thiourea: synthesis and crystal structure of di-µ-hydrogencyanamido(1–)-bis[(N,N′,N″-trimethyl-1,4,7-triazacyclononane)copper(II)] di-perchlorate monohydrate

P. Chaudhuri, K. Wieghardt, B. Nuber and J. Weiss, J. Chem. Soc., Chem. Commun., 1985, 265 DOI: 10.1039/C39850000265

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