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Issue 4, 1985
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Oxidative activation of CoII in Schiff base complexes in the presence of n-butyltin trichloride: the molecular structure of BunSn(OMe)Cl2·CoCl(salen)[salen =N,N′-ethylenebis(salicylideneaminato)]

Abstract

Air stable chloroform solutions of Schiff base complexes of CoII undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BunSn(OMe)Cl2·CoCl-(salen)[salen =N,N′-ethylenebis(salicylideneaminato)], the cobalt(III) Schiff base species behave as Lewis bases towards tin(IV).

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Article information


J. Chem. Soc., Chem. Commun., 1985, 231-232
Article type
Paper

Oxidative activation of CoII in Schiff base complexes in the presence of n-butyltin trichloride: the molecular structure of BunSn(OMe)Cl2·CoCl(salen)[salen =N,N′-ethylenebis(salicylideneaminato)]

D. Cunningham, T. Higgins, B. Kneafsey, P. McArdle and J. Simmie, J. Chem. Soc., Chem. Commun., 1985, 231
DOI: 10.1039/C39850000231

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