Structure and magnetic properties of novel 1,1-azido-bridged and 1,1-cyanato-bridged binuclear copper(II) complexes
Abstract
The crystal structures and the magnetic properties of two novel complexes, of formula [Cu2(C17H27N4O)(C2H3O2)L]PF6, L = N3 or NCO, with a 1,1-azido or cyanato bridge in addition to phenolato and acetato bridges have been investigated and the relevance of the results to the fields of molecular magnetism and bioinorganic chemistry is discussed.