The dioxaborinane derivatives, which were synthesized by a method including a new Pd-catalysed coupling reaction, form mesomorphic phases in a wide temperature range, and provide a new series of liquid crystalline compounds containing a boron atom in the principal structure.
K. Seto, S. Takahashi and T. Tahara, J. Chem. Soc., Chem. Commun., 1985, 122 DOI: 10.1039/C39850000122
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