The one-electron oxidation and one-electron reduction of Re2(µ-Cl)2(µ-dppm)2Cl4(dppm = Ph2PCH2PPh2) can be accomplished using NOPF6 and cobaltocene as the oxidant and reductant, respectively, to give paramagnetic ions that possess metal–metal bond orders of 1.5.
K. R. Dunbar, D. Powell and R. A. Walton, J. Chem. Soc., Chem. Commun., 1985, 114 DOI: 10.1039/C39850000114
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