The volume of activation for electron transfer between the aqueous manganate and permanganate ions by the cation-independent pathway is much more negative (–21 ± 1 cm3 mol–1 at 45 °C and ionic strength 1.1 mol l–1) than can be accounted for by conventional theory.
L. Spiccia and T. W. Swaddle, J. Chem. Soc., Chem. Commun., 1985, 67 DOI: 10.1039/C39850000067
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