Iodosylbenzene, catalysed by tetraphenylporphyrinato-iron(III) or-manganese(III) chloride, oxidises tertiary amines by an initial one-electron transfer process whereas with t-butyl hydroperoxide with these catalysts the oxidation is initiated by hydrogen atom abstraction.
J. R. L. Smith and D. N. Mortimer, J. Chem. Soc., Chem. Commun., 1985, 64 DOI: 10.1039/C39850000064
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