Metal ions with small ionic radii promote the selective O–S bond cleavage of phenyl phosphosulphate, whereas those with larger ionic radii catalyse the selective P–O bond cleavage of phenyl phosphosulphate.
T. Eiki, T. Ogihara, A. Kato, F. Arai and W. Tagaki, J. Chem. Soc., Chem. Commun., 1985, 49 DOI: 10.1039/C39850000049
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