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Issue 12, 1985
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An air-stable d9 nickel(I) catenate: stabilisation of monovalent nickel by interlocked macrocyclic ligands

Abstract

The catenand cat-30 forms a d9 nickel(I) complex by electroreduction of the nickel(II) precursor, Ni(cat-30)2+; owing to the particular arrangement of the co-ordinating subunits and to the special topology of the ligand, the nickel(I) complex displays exceptional redox stability.

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Article information


J. Chem. Soc., Chem. Commun., 1985, 760-762
Article type
Paper

An air-stable d9 nickel(I) catenate: stabilisation of monovalent nickel by interlocked macrocyclic ligands

C. O. Dietrich-Buchecker, J. Kern and J. Sauvage, J. Chem. Soc., Chem. Commun., 1985, 760
DOI: 10.1039/C39850000760

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