Thermodynamic and kinetic parameters have been measured for the reaction of triethylphosphine with carbon disulphide in several non-aqueous solvents. The observed free energy, entropy, and enthalpy values are discussed in terms of solvation of the reactants, products, and transition state, using regression on solvent parameters.
F. I. W. and J. G. S. B., J. Chem. Soc., Perkin Trans. 2, 1984, 1323 DOI: 10.1039/P29840001323
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