The reaction of 2,4,6-trinitrobenzyl chloride with dilute aqueous sodium hydroxide gives a σ-adduct by hydroxide ion attck at the 1-position. Kinetic and equilibrium data for this reaction are reported and are compared with those for the reaction with methoxide ions in methanol.
M. R. Crampton, P. J. Routledge and P. Golding, J. Chem. Soc., Perkin Trans. 2, 1984, 939 DOI: 10.1039/P29840000939
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