A study has been made of the rearrangement of derivatives of the eudesmane sesquiterpene, (+)-rosifoliol (3), to valencane structures. This biogenetically significant methyl migration has been accomplished via Lewis acid-catalysed epoxide opening.
R. Ramage and I. A. Southwell, J. Chem. Soc., Perkin Trans. 1, 1984, 1323 DOI: 10.1039/P19840001323
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