Issue 10, 1984

Novel ultraviolet product spectra in the photolysis of chlorine dioxide

Abstract

U.v. absorption spectra have been recorded during the low-intensity photolysis of chlorine dioxide, OClO, using a diode-array spectrometer. A broad-band u.v. spectrum was observed which was favoured by low temperature and high OClO pressure. The absorption could be explained only in part by the presence of ClO dimer, Cl2O2. Unequivocal assignment of the residual spectrum was not possible but it may be due to the chlorine perchlorate molecule, ClOClO3, a recently discovered product of OClO photolysis.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1984,80, 2737-2743

Novel ultraviolet product spectra in the photolysis of chlorine dioxide

R. A. Barton, R. A. Cox and T. J. Wallington, J. Chem. Soc., Faraday Trans. 1, 1984, 80, 2737 DOI: 10.1039/F19848002737

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