A thermodynamic model for the ion exchange of K, NH4 and Cs on the ion exchanger cobalt(II)–hexacyanoferrate(II)–M where M = K,NH4 and Cs, has been postulated. Based on the experimentally determined thermodynamic functions ΔG⊖exp, ΔS⊖exp and ΔH⊖exp and on the calculated values of excess functions, the deviations from ideality of the investigated reactions have been explained.
T. S. Ćeranić, J. Chem. Soc., Faraday Trans. 1, 1984, 80, 823 DOI: 10.1039/F19848000823
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