Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 5, 1984
Previous Article Next Article

A convenient synthesis of [Ru(η-C5H5)(PPh3)(CO)Cl] and the cations [Ru(η-C5H5)(PPh3)L(CO)]+[L = CO, PMe3, or P(OPh)3]

Abstract

Treatment of [Ru(η-C5H5)(PPh3)2Cl] with sulphur under carbon monoxide at 1–3 atm in hot toluene gives quantitative yields of [Ru(η-C5H5)(PPh3)(CO)Cl], which can be further treated in warm methanol with CO, PMe3, and P(OPh)3 to give the cations [Ru(ηC5H5)(PPh3)(CO)2]+, [Ru(η-C5H5)(PPh3)(PMe3)(CO)]+, and [Ru(η-C5H5)(PPh3){P(OPh)3}(CO)]+ respectively.

Back to tab navigation

Article type: Paper
DOI: 10.1039/DT9840000993
Citation: J. Chem. Soc., Dalton Trans., 1984,0, 993-994

  •   Request permissions

    A convenient synthesis of [Ru(η-C5H5)(PPh3)(CO)Cl] and the cations [Ru(η-C5H5)(PPh3)L(CO)]+[L = CO, PMe3, or P(OPh)3]

    S. G. Davies and S. J. Simpson, J. Chem. Soc., Dalton Trans., 1984, 0, 993
    DOI: 10.1039/DT9840000993

Search articles by author

Spotlight

Advertisements