According to published spectral data, unnoticed Voigt reactions of acetoin yielded the expected α-(alkylamino) ketones which formed α-(dialkylamino)ketones on alkylation.
R. Friary and G. W. Kirby, J. Chem. Soc., Chem. Commun., 1984, 1383a DOI: 10.1039/C3984001383A
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