The reaction of 5,6-dimethylene-1,4-dimethyl-2,3-diphenylnorborn-2-en-7-one (6) with dienophile, is used as a probe for π-facial selectivity in Diels–Alder reactions and is shown to proceed through norbornadien-7-ones, one of which exhibits moderate stability.
R. N. Warrener, R. A. Russell and I. G. Pitt, J. Chem. Soc., Chem. Commun., 1984, 1675 DOI: 10.1039/C39840001675
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