Issue 24, 1984

Novel photoreactions of styrylcyclopropanes via photo-induced electron transfer

Abstract

9,10-Dicyanoathracene-sensitized photoreaction of styrylcyclopropanes in the presence of Cu(BF4)2 in MeCN–MeOH gives α-cyclopropyl nenzyl ketones as major products, which are produced via a two-electron oxidation of styrylcyclopropanes followed by a 1,2-migration of the cyclopropyl group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1665-1667

Novel photoreactions of styrylcyclopropanes via photo-induced electron transfer

K. Mizuno, K. Yoshioka and Y. Otsuji, J. Chem. Soc., Chem. Commun., 1984, 1665 DOI: 10.1039/C39840001665

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