Acid-catalysed reaction of D-camphorquinone with racemic 1,2-diols (e.g. 3-chloropropane-1,2-diol)under kinetically controlled conditions yields a predominant diasteroisomeric acetal, that can be easily converted into an optically pure epoxide.
M. K. Ellis, B. T. Golding and W. P. Watson, J. Chem. Soc., Chem. Commun., 1984, 1600 DOI: 10.1039/C39840001600
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