Addition of methanol to W(PMe3)4(η2-CH2PMe2)H gives the η2-formaldehyde derivative W(PMe3)4(η2-CH2O)H2 which reacts sequentially with dihydrogen forming initially the methoxyhydrido compound W(PMe3)4(OMe)H3 and then W(PMe3)4H4 accompanied by the production of MeOH.
M. L. H. Green, G. Parkin, K. J. Moynihan and K. Prout, J. Chem. Soc., Chem. Commun., 1984, 1540 DOI: 10.1039/C39840001540
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