Issue 22, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Reversible intramolecular electron transfer within a ruthenium(III) porphyrin-ruthenium(II) porphyrin π-cation radical system induced by changes in axial ligation

Mark H. Barley,   David Dolphin  and  Brian R. James  

Abstract

Reaction of the octaethylporphyrinatobis(triphenylarsine)ruthenium(III) cation with CO generates the carbonyl(triphenylarsine)ruthenium(II) porphyrin π-cation radical species viaan intramolecular electron transfer; the process is quantitatively reversible.

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Article information

DOI
https://doi.org/10.1039/C39840001499
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1499-1500

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Reversible intramolecular electron transfer within a ruthenium(III) porphyrin-ruthenium(II) porphyrin π-cation radical system induced by changes in axial ligation

M. H. Barley, D. Dolphin and B. R. James, J. Chem. Soc., Chem. Commun., 1984, 1499 DOI: 10.1039/C39840001499

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