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Issue 22, 1984
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The influence of carbanion orbital orientation and charge distribution on the structures of polylithium compounds

Abstract

Symmetrical (C2v) double bridging, commonly exhibited by 1,4-dilithium compounds e.g. in (1) and (2), is not favoured in (4) and (5) since charge deloclization in the dianion, hybridization, and orbital orientation effects are more important than quadrupole-like electrostatic interactions (3).

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Article information


J. Chem. Soc., Chem. Commun., 1984, 1495-1496
Article type
Paper

The influence of carbanion orbital orientation and charge distribution on the structures of polylithium compounds

P. von Ragué Schleyer, A. J. Kos, D. Wilhelm, T. Clark, G. Boche, G. Decher, H. Etzrodt, H. Dietrich and W. Mahdi, J. Chem. Soc., Chem. Commun., 1984, 1495
DOI: 10.1039/C39840001495

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