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Issue 22, 1984
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Formation of η-cyclopentadienylpentahydrido(trimethylphosphine)tungsten from cyclopentane, trimethylphosphine, and tungsten atoms

Abstract

Co-condensation of tungsten atoms with cyclopentane and trimethylphosphine gives inter alia, W(η-C5H5)(PMe3)H5; when cyclopentane is replaced by cyclopentene, W(η-C5H5)(PMe3)2H3 and W(η-C5H5)(PMe3)2(η-C5H8)H are formed which on treatment with dihydrogen form the pentahydride W(η-C5H5)(PMe3)H5.

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Article information


J. Chem. Soc., Chem. Commun., 1984, 1467-1468
Article type
Paper

Formation of η-cyclopentadienylpentahydrido(trimethylphosphine)tungsten from cyclopentane, trimethylphosphine, and tungsten atoms

M. L. H. Green and G. Parkin, J. Chem. Soc., Chem. Commun., 1984, 1467
DOI: 10.1039/C39840001467

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