An X-ray structure analysis and magetic as well as electrochemical data for synthetic corrinioid and corphinoid nickel(II) complexes document the pronounced axial electrophilicity of the nickel(II) ion when complexed by ligands of the type occurring in coenzyme F430.
C. Kratky, A. Fässler, A. Pfaltz, B. Kräutler, B. Jaun and A. Eschenmoser, J. Chem. Soc., Chem. Commun., 1984, 1368 DOI: 10.1039/C39840001368
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