In the complex [Os(BH4)H3{P(c-C5H9)3}2](c-C5H9= cyclo-C5H9), prepared quantitatively from the reaction of [OsH6{P(c-C5H9)3}2] with BH3·thf, (thf = tetrahydrofuran), the tetrahydroborate ligand is bound to the metal by two bridging hydrogen atoms which, at 90 °C, exchange rapidly only with the hydride ligands on osmium.
P. W. Frost, J. A. K. Howard and J. L. Spencer, J. Chem. Soc., Chem. Commun., 1984, 1362 DOI: 10.1039/C39840001362
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