Issue 20, 1984

A new synthesis and i.r. characterisation of chromium hexafluoride

Abstract

A convenient synthesis of CrF6 from CrO3 and F2(170 °C/25 atm/72 h) is described; it is characterized by matrix-isolation i.r. spectroscopy, and using this technique there is wvidence that molecular CrF6 undergoes thermal decomposition to CrF4 at low pressures.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1355-1356

A new synthesis and i.r. characterisation of chromium hexafluoride

E. G. Hope, P. J. Jones, W. Levason, J. S. Ogden and M. Tajik, J. Chem. Soc., Chem. Commun., 1984, 1355 DOI: 10.1039/C39840001355

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