[Rh4(CO)9([graphic omitted]H2)] adopts a ‘butterfly’ rhodium skeleton with a CO bridging the wing -tip atoms in the crystal and in solution; at ambient temperature in solution, the rhodium skeleton is non rigid with the inter wing-tip vector exchanging between three adjacent positions.
R. J. Crowte, J. Evans and M. Webster, J. Chem. Soc., Chem. Commun., 1984, 1344 DOI: 10.1039/C39840001344
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