Carbocyclisation of a hex-5-enopyranoside of D-arabino configuration under modified Ferrier's conditions gave chiral substituted cyclohexanes, which are precursors of aminocyclitols and useful synthetic intermediates, in good yield and without side reactions.
F. Chretien and Y. Chapleur, J. Chem. Soc., Chem. Commun., 1984, 1268 DOI: 10.1039/C39840001268
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