Issue 18, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Biosynthesis of the meroterpenoid, austin, by Aspergillus ustus: incorporation of 18O2, sodium [1-13C, 18O2]acetate, and [Me-13C, 2H3]methionine

Thomas J. Simpson,   Desmond J. Stenzel,   Richard N. Moore,   Laird A. Trimble  and  John C. Vederas  

Abstract

Mass spectral and 13C n.m.r. analyses of austin (1) produced by fermentation of Aspergillus ustus in the presence of 18O2 and [Me-13C,2H3]methionine showed that all labelled methionine-derived hydrogens were retained, determined that five of nine oxygens were introduced by aerobic oxidation, and elucidated the general mechanism of late biosynthetic stages.

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Article information

DOI
https://doi.org/10.1039/C39840001242
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1242-1243

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Biosynthesis of the meroterpenoid, austin, by Aspergillus ustus: incorporation of 18O2, sodium [1-13C, 18O2]acetate, and [Me-13C, 2H3]methionine

T. J. Simpson, D. J. Stenzel, R. N. Moore, L. A. Trimble and J. C. Vederas, J. Chem. Soc., Chem. Commun., 1984, 1242 DOI: 10.1039/C39840001242

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