Highly unsaturated three-bladed propeller molecules. Synthesis and ring inversion dynamics of two [4.4.4]propellatrienetriones
Abstract
The kinetic parameters for antipodal ring inversion were measured for two [4.4.4]propellatrienetriones; the ΔG‡(298K) values show the incorporation of three–CH
CHCO– units does little to increase the barrier and allow for their possible isolation in optically active form.
Please wait while we load your content...