Nitric oxide is dissociatively chemisorbed at a Zn(0001)surface at 80 K, both the chemisorbed nitrogen and oxygen are stable up to 470K; in the presence of coadsorbed water, hydrogenation of the adsorbed nitrogen occurs at 200K by hydroxyl species formed as a result of the activation of molecularly adsorbed water by chemisorbed oxygen generated in the dissociative chemisorption of NO.
C. T. Au, M. W. Roberts and A. R. Zhu, J. Chem. Soc., Chem. Commun., 1984, 737 DOI: 10.1039/C39840000737
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