Synthesis of (–)-ajmalicine from (–)-tryptophan
Abstract
(–)-Tryptophan has been converted into(–)-ajmalicine in 15 steps; the key step is an intramolecular Michael reaction in which the C(15)–C(20) bond is formed with full stereocontrol.
(–)-Tryptophan has been converted into(–)-ajmalicine in 15 steps; the key step is an intramolecular Michael reaction in which the C(15)–C(20) bond is formed with full stereocontrol.
G. Massiot and T. Mulamba, J. Chem. Soc., Chem. Commun., 1984, 715 DOI: 10.1039/C39840000715
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