Stereospecific addition of Me2Cu(CN)Li2 to a bicyclic conjugated lactone, derived from D-glucose viaan intram olecular Wadsworth–Emmons reaction, affords a rational route to introduce a chiral centre at C-6 on the glucose skeleton.
D. Nicoll-Griffith and L. Weiler, J. Chem. Soc., Chem. Commun., 1984, 659 DOI: 10.1039/C39840000659
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