Acid catalysed isopropenyl acetate treatment of vinyl sulphoxides results in a formal oxygen transposition from sulphur to the β-olefinic carbon via a presumed [3,3]-sigmatropic rearrangement of an acetoxysulphonium salt.
O. De Lucchi, G. Marchioro and G. Modena, J. Chem. Soc., Chem. Commun., 1984, 513 DOI: 10.1039/C39840000513
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