X-Ray structural analysis of the copper (II)complex of the pyridoxylidenehistamine Schiff's base, [Cu(C13H16N4O2)CI2], shows that the copper atom is square-pyramidally co-ordinated by the tridentate Schiff's base through the imino and imidazole nitrogens and the phenolate oxygen, and by a chlorine atom; another chlorine atom occupies a fifth, axial site.
K. Aoki and H. Yamazaki, J. Chem. Soc., Chem. Commun., 1984, 410 DOI: 10.1039/C39840000410
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