SCHEDULED MAINTENANCE
Imido complexes of niobium and tantalum(V) are prepared by the reaction of the pentachlorides with Me3SiNHBut: with excess of t-butylamine, imido, amido, and amino ligands are formed about the same metal centre, as shown in an X-ray crystallographic study of the title complex.
T. C. Jones, A. J. Nielson and C. E. F. Rickard, J. Chem. Soc., Chem. Commun., 1984, 205 DOI: 10.1039/C39840000205
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