Mechanism of elimination from a tightly hydrogen-bonded carbanion
Abstract
The base-promoted 1,2-elimination reaction of(1; R = OAc) with 1,4-diazabicyclo[2.2.2]octane in methanol is concluded to have a reverse stepwise preassociation mechanism.
The base-promoted 1,2-elimination reaction of(1; R = OAc) with 1,4-diazabicyclo[2.2.2]octane in methanol is concluded to have a reverse stepwise preassociation mechanism.
A. Thibblin, J. Chem. Soc., Chem. Commun., 1984, 92 DOI: 10.1039/C39840000092
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