The adduct (4) of bicyclohept-1-en-1-yl and 2,5-dimethyl-p-benzoquinone on exposure to light isomerizes to the pentacyclic product (3) by a long range hydrogen migration which has been previously observed in analogous systems under electron impact.
A. Weisz, M. Kaftory, I. Vidavsky and A. Mandelbaum, J. Chem. Soc., Chem. Commun., 1984, 18 DOI: 10.1039/C39840000018
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