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Issue 16, 1984
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Michael additions of hydrazones for carbon–carbon bond formation

Abstract

The lithium salts of t-butyl-and trityl-hydrazones react with methyl crotonate to form C-trapped azo-esters and similar products were observed from a thermal ene-reaction of aldehyde t-butylhydrazones with methyl acrylate or acrylonitrile, and aldehyde phenylhydrazones with methyl acrylate; these products can be diverted into synthetically useful γ-keto-esters, γ-keto-nitriles, saturated esters, γ-alkyl-2-pyrrolidones, and γ-amino-esters.

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Article information


J. Chem. Soc., Chem. Commun., 1984, 1095-1096
Article type
Paper

Michael additions of hydrazones for carbon–carbon bond formation

J. E. Baldwin, R. M. Adlington, J. C. Bottaro, A. U. Jain, J. N. Kolhe, M. W. D. Perry and I. M. Newington, J. Chem. Soc., Chem. Commun., 1984, 1095
DOI: 10.1039/C39840001095

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