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Issue 13, 1984
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Preparation and crystal structure of the argentate complex [Li(tetrahydrofuran)4][Ag{C(SiMe3)3}2]

Abstract

The product of the reaction between AgI and tris(trimethylsilyl)methyl-lithium in tetrahydrofuran (thf) has been shown by X-ray diffraction to be the ionic ate complex [Li(thf)4][Ag{C(SiMe3)3}2]; evidence is presented that this and the analogous ate complexes of lithium and copper retain their structures in solution.

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Article information


J. Chem. Soc., Chem. Commun., 1984, 870-871
Article type
Paper

Preparation and crystal structure of the argentate complex [Li(tetrahydrofuran)4][Ag{C(SiMe3)3}2]

C. Eaborn, P. B. Hitchcock, J. D. Smith and A. C. Sullivan, J. Chem. Soc., Chem. Commun., 1984, 870
DOI: 10.1039/C39840000870

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