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Issue 13, 1984
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Acid catalysed stereomutations about the C(2)–C(3) bond of 3-aryl-1-methoxyallyl cations. Dication formation by oxygen protonation

Abstract

The thermally induced cis to trans isomerization of 3-aryl-1-methoxyallyl cations in superacid media is shown to occur by formation of an intermediate O-protonated dication.

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Article information


J. Chem. Soc., Chem. Commun., 1984, 812-813
Article type
Paper

Acid catalysed stereomutations about the C(2)–C(3) bond of 3-aryl-1-methoxyallyl cations. Dication formation by oxygen protonation

C. Blackburn and R. F. Childs, J. Chem. Soc., Chem. Commun., 1984, 812
DOI: 10.1039/C39840000812

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