CX3+ ions (X = H, T), formed by the spontaneous β– decay of CX4, were allowed to react with gaseous CH3Y (Y = F, Cl, and Br) in the presence of a trace amount of toluene. The formation of radioactive isomeric xylenes, arising from the attack of CH3YCH3+ ion to C7H8, is discussed.
M. Colosimo and R. Bucci, J. Chem. Soc., Perkin Trans. 2, 1983, 933 DOI: 10.1039/P29830000933
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