Tetrakis(methylthio)ethene as a bidentate chelating and quadridentate bridging thioether
Abstract
In the complex [PtClMe{(MeS)2C
C(SMe)2}] the thioether functions as a bidentate chelate, and in [(PtBrMe3)2(MeS)2C
C(SMe)2] as a bridging quadridentate ligand. In both compounds sulphur inversion is fast at room temperature.
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