Regioselective chlorination of valine derivatives establishes the chemical validity of a regiospecific hydrogen-atom abstraction proposed in penicillin biosynthesis and provides a viable synthetic method for direct and selective functionalisation of these compounds.
C. J. Easton and N. J. Bowman, J. Chem. Soc., Chem. Commun., 1983, 1193b DOI: 10.1039/C3983001193B
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